Based on the information, it seems that the new team members are going to have quite the challenge to deal with as Oliver will be assembling a new version of Team Arrow in the coming few episodes. You can check out the official description below, but be aware of some potential spoilers.
“Penance” — (8:00-9:00 p.m. ET) (TV-14, LV) (HDTV)
OLIVER STEPS IN FOR DIGGLE — Oliver (Stephen Amell) and Lyla (guest star Audrey Marie Anderson) team up on a secret mission for Diggle (David Ramsey). Felicity (Emily Bett Rickards) finds out and disapproves of the plan and opts to stay behind. When Tobias Church (guest star Chad L. Coleman) launches a deadly assault against the city, Felicity must decide if she wants to send the recruits out sans the Green Arrow. Dermott Downs directed the episode written by Brian Ford Sullivan & Oscar Balderrama (#504). Original airdate 10/26/2016.”
Arrow Season 5 airs on Wednesday nights at 8/7c on The CW.
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The film will also be set in Central City.